Browse Topic: Oxygen

Items (383)
ABSTRACT
Ard, DennisPetrassi, FrankTemme, LeonardBowers,  BobbyHayes,  AmandaSt.Onge,  PaulMcAtee, Aaron
This standard is intended to apply to portable compressed gaseous oxygen equipment. When properly configured, this equipment is used either for the administration of supplemental oxygen, first aid oxygen or smoke protection to one or more occupants of either private or commercial transport aircraft. This standard is applicable to the following types of portable oxygen equipment: a Continuous flow 1 Pre-set 2 Adjustable 3 Automatic b Demand flow 1 Straight-demand 2 Diluter-demand 3 Pressure-demand c Combination continuous flow and demand flow.
A-10 Aircraft Oxygen Equipment Committee
This specification covers an aluminum alloy in the form of pre-alloyed powder.
AMS AM Additive Manufacturing Metals
G-3, Aerospace Couplings, Fittings, Hose, Tubing Assemblies
This list of terms, with accompanying photomicrographs where appropriate, is intended as a guide for use in the preparation of material specifications.
AMS G Titanium and Refractory Metals Committee
This specification covers a premium aircraft-quality maraging steel in the form of bars 0.50 inch (12.7 mm) and over in nominal diameter or least distance between parallel sides, forgings, and forging stock.
AMS E Carbon and Low Alloy Steels Committee
This specification covers an aluminum alloy in the form of pre-alloyed powder.
AMS AM Additive Manufacturing Metals
Low Pressure Carburization (LPC) is widely used in the aerospace industry for hardening components made of steels with high alloy content and high heat resistant properties. The traditional gas carburizing process often generates Intergranular Oxidation (IGO) near the surface due to the existence of oxygen in the furnace atmosphere, which needs to be removed by grinding after hardening to restore bending and contact fatigue performance. LPC processing is done in a low pressure chamber without the existence of oxygen, so the surface microstructure is improved by eliminating IGO. High temperature resistant steels require high alloy element contents, and some elements are strong carbide formers, such as Cr, Mn, Mo, and V, etc. During LPC processing, both iron and alloy carbides can be formed, which significantly affect the carburization time required to reach a specified case depth and surface carbon. The carbides formed during the LPC process may not decompose completely prior to quench hardening, and these primary carbides will end up in the final processed parts. If the size of these primary carbides is not controlled, both bending and contact fatigue performance may be decreased. In order to control carbide formation during LPC, the carbon diffusivity of a material must be characterized. This characterization was recently performed under a program between DANTE Solutions and the Combat Capabilities Development Command Aviation and Missile Center (CCDC AvMC). In this research, a specifically designed coupon was used to characterize the carbon diffusivity and carbide forming properties during LPC processes. Using the characterized material properties, LPC process recipes can be designed by using modeling to achieve specific case depth and surface carbon content. The work was demonstrated using Pyrowear 675 steel and DANTE commercial heat treatment modeling software.
Li, ZhichaoFetty, JasonSims, JustinFerguson, LynnBaker, Treven
Numerical Investigation on Effects of Combustion Chamber Structure and Oxygen Enriched Air on Combustion and Emission Characteristics of Marine Diesel Engine2018-01-17869/10/2018
In order to improve the combustion and emissions for high-speed marine diesel engines, numerical investigations on effects of different combustion chamber structures combined with oxygen enriched air have to be conducted. The study uses AVL Fire code to establish three-dimensional combustion model and simulate the in-cylinder flow, air-fuel mixing and combustion process with the flow dynamics metrics such as swirl number and uniformity index, analyze the interactional effects of combustion chamber structures and oxygen enriched air against the experimental data for a part load operation at 1350 r/min, find the optimized way to improve engine performance as well as decrease the NOx and soot emissions. The novelty is that this study is to combine different oxygen concentration with different combustion chamber structures including the re-entrant chamber, the straight chamber and the open chamber. Results show that the chamber diameter, bowl depth, oxygen enrichment can greatly influence in-cylinder flow, the re-entrant chamber makes a higher power output at the price of a smaller increase of NOx emissions, meanwhile the chamber combined with suitable oxygen concentration can enhance the in-cylinder peak pressure and temperature, decrease the soot emissions and cause more NOx emissions. The straight chamber has lower emissions at the same output power level compared with the prototype, the open chamber is found to have a lower output power.
Zhao, ChangpuHuang, SiruiWang, Ke
This specification covers an arc-cast molybdenum alloy in the form of round bars 0.125 to 4.5 inches (3.00 to 112.50 mm), inclusive.
AMS G Titanium and Refractory Metals Committee
This specification covers a titanium alloy in the form of sheet in nominal thicknesses 0.016 through 0.1874 inch (0.41 through 4.760 mm).
AMS G Titanium and Refractory Metals Committee
Mechanisms of Enhanced Reactivity with Ozone Addition for Advanced Compression Ignition2018-01-12494/3/2018
Mechanisms responsible for enhanced charge reactivity with intake added ozone (O3) were explored in a single-cylinder, optically accessible, research engine configured for low-load advanced compression ignition (ACI) experiments. The influence of O3 concentration (0-40 ppm) on engine performance metrics was evaluated as a function of intake temperature and start of injection for the engine fueled by iso-octane, 1-hexene, or a 5-component gasoline surrogate. For the engine fueled by either the gasoline surrogate or 1-hexene, 25 ppm of added O3 reduced the intake temperature required for stable combustion by 65 and 80°C, respectively. An ultraviolet (UV) light absorption diagnostic was also used to measure crank angle (CA) resolved in-cylinder O3 concentrations for select motored and fired operating conditions. The O3 measurements were compared to results from complementary 0D chemical kinetic simulations that utilized detailed chemistry mechanisms augmented with O3 oxidation chemistry. From the measurements, rapid thermally induced O3 decomposition was observed during the compression stroke shortly before top dead center (TDC). Ozone decomposition advanced when the charge temperature was increased, oxygen concentration was reduced, or fuel was added. While the model well captures the experimental trends, for unfueled conditions the temporal prediction of O3 decomposition is generally too far retarded. The modeling further indicates the O3 decomposition leads to a burst of highly reactive atomic oxygen (O). For fueled conditions, the O rapidly abstracts fuel hydrogen to form hydroxyl (OH), which then leads to the substantial formation of hydroperoxyl (HO2) and hydrogen peroxide (H2O2). Strong UV light absorbance shortly after O3 decomposition confirms the presence of these species in the experiments. The in situ measurements are expected to aid kinetic model development of O3 decomposition processes and the associated influence of formed radicals on autoignition kinetics.
Ekoto, IsaacFoucher, Fabrice
Modelling the Variation in Precious Metal Dispersion in a Three Way Catalytic Converter after Aging2018-01-09594/3/2018
With emission legislations becoming ever more stringent, there is an increased pressure on after-treatment systems and more specifically three-way catalysts. With recent developments in emission legislations, there is a requirement for more complex after-treatment systems and understanding of the aging process. Whilst the body of understanding on catalyst deactivation and, in particular, catalyst aging is growing, there are still significant gaps in understanding, particularly how real world variations in temperature, flow rate and gas concentrations affect catalyst behavior. Under normal driving conditions, the catalyst can experience varying oxygen concentrations, such as under heavy acceleration or cruising down a hill will show a variation in oxygen from the engine emissions. The effect that varying oxygen concentrations has on the rate of aging is not fully understood and hence the total deactivation and conversion efficiencies are not known throughout the catalyst lifetime. Traditionally, catalyst specification has relied heavily on catalyst testing over a wide range of mileage, with catalyst aging being conducted via vehicle/bench testing, focusing on 3 main parameters; flow (space velocity), temperature (inlet/bed) and lambda (oxygen concentration). The main drawback of this approach, particularly in the early stages of powertrain development, is the cost and resource required to conduct the testing. It is in this area of development that a kinetic model to predict the catalyst performance taking into account aging time, temperature, flow rate and exposure to oxygen concentration would be of great benefit. This paper presents a continuation of previous work into the investigation of the effect of varying oxygen concentration on the rate of catalyst aging. A number of commercially available palladium three-way catalysts were aged over a precise temperature cycle at varying oxygen concentrations for different aging times related back to a mileage. The results were analyzed in detail and fed into a catalyst model in which a built in optimizer calculated the initial pre-exponential and activation energy for characterization tests. Once optimized, the model then calculated the variation in dispersion for the catalysts aged under varying levels of oxygen at a range of set mileage. The variation in dispersion over aging is presented and compared with predictions based on the standard aging algorithm and with others proposed in literature.
Irwin, KurtisDouglas, RoyStewart, Jonathan DavidPedlow, AndrewWoods, Andrew
A New Catalyzed HC Trap Technology that Enhances the Conversion of Gasoline Fuel Cold-Start Emissions2018-01-09384/3/2018
Passive in-line catalyzed hydrocarbon (HC) traps have been used by some manufacturers in the automotive industry to reduce regulated tailpipe (TP) emissions of non-methane organic gas (NMOG) during engine cold-start conditions. However, most NMOG molecules produced during gasoline combustion are only weakly adsorbed via physisorption onto the zeolites typically used in a HC trap. As a consequence, NMOG desorption occurs at low temperatures resulting in the use of very high platinum group metal (PGM) loadings in an effort to combust NMOG before it escapes from a HC trap. In the current study, a 2.0 L direct-injection (DI) Ford Focus running on gasoline fuel was evaluated with full useful life aftertreatment where the underbody converter was either a three-way catalyst (TWC) or a HC trap. A new HC trap technology developed by Ford and Umicore demonstrated reduced TP NMOG emissions of 50% over the TWC-only system without any increase in oxides of oxygen (NOx) emissions. Other HC trap technologies had at best a 25% NMOG emission reduction. Parallel laboratory reactor studies were conducted in an effort to understand the improved trapping and NMOG combustion features of the newly developed HC trap. Increased trapping efficiency of certain aromatics (toluene) and alkenes (2-methylpropene) was assigned to rapid and efficient polymerization of these species due to a combination of strong Brønsted acidity, precious metal (i.e., Pd), and base redox active metals. During the emissions desorption phase, the combustion of the adsorbed NMOG occurred without gas-phase oxygen due to the delayed desorption of the large NMOG molecules coupled with the high activity of the base redox active metal in the presence of steam. Besides acting as a source of oxygen during combustion, the ion-exchanged form of the base metal also stabilized Pd against sintering during the hot, four-mode aging process.
Lupescu, JasonXu, LifengJen, Hung-WenHarwell, AmyNunan, JohnAlltizer, ChadDenison, Gregory
A Mechanistic Analysis of Oxygen Vacancy Driven Conductive Filament Formation in Resistive Random Access Memory Metal/NiO/Metal Structures18AERP02_092/1/2018
Study could lead to more efficient electrically switchable resistive random access memory devices. Air Force Research Laboratory, Wright-Patterson Air Force Base, Dayton, Ohio Resistive Random Access Memory (RRAM) devices have drawn much interest in the last decade, particularly the concept of a memristor. In this case, the so-called memristance, which provides the relationship between the change in charge (time integral of the current) and flux (time integral of the voltage), is not a constant as in linear elements, but a function of the charge, resulting in a nonlinear circuit element. Applications of such two-terminal electrical devices that provide high densities and low-power operation include, for instance, neuromorphic-type computing elements. This area of research led to a study on the effects of ionizing radiation on such devices. Significant focus on filamentary- type resistive switching (RS) mechanisms emerged, where formation/rupture of a conductive filament (CF) ensures successive switching in the nonvolatile metal-insulator-metal (MIM) memristors, dependent on the switching material. In such a RRAM device, binary oxide MIM structures are constructed using an insulating layer stacked between two electrodes, which can be built either symmetrically or asymmetrically using the same or different top or bottom electrodes, respectively.
Simultaneous Measurement of the Flame Lift-Off Length on Direct Injection Diesel Sprays Using High Speed Schlieren Imaging and OH Chemiluminescence2017-01-230710/8/2017
Lift-off length is defined as the distance from injector hole to the location where flame stabilized on a high injection pressure direct injection (DI) diesel spray. In this paper we used the high-speed (40 kHz) Schlieren and time-averaged OH chemiluminescence imaging technique to simultaneously measure the flame lift-off locations on a DI diesel spray in an optically accessible and constant-volume combustion vessel. The time-resolved development of the diesel spray acquired from the high-speed Schlieren imaging system enabled us to observe the instantaneous spray structure details of the spray flames. The OH chemiluminescence image obtained from a gated, intensified CCD video camera with different delay and width settings was used to determine the quiescent lift-off length. Experiments were conducted under various ambient temperatures, ambient gas densities, injection pressures and oxygen concentrations. From the Schlieren images of the injecting procedure, along the axis of the spray from the injector hole, a distinct expansion located in the downstream, after which the edge of the spray changed to transparent gradually and the refractive index gradients started to diminish. This point was defined as the flame location of high-speed Schlieren and the length from it to the injector was employed as the lift-off length. It is found that the Schlieren imaging lift-off length fluctuated within a certain range during the injection process, and the average lift-off length of quiescent conditions was also measured based on the OH chemiluminescence image. The results of the high-speed Schlieren imaging coincided well with the lift-off length results acquired from the CCD results, indicating high-speed Schlieren imaging technique can be used to measure the flame lift-off length on DI diesel spray.
Wei, YijieLi, TieWang, BinShi, Weiquan
Evaluation of the Stability and Ignition Quality of Diesel-Biodiesel-Butanol Blends2017-01-232010/8/2017
FAME is the most common renewable component of conventional automotive diesel. Despite the advantages, biodiesel is more susceptible to oxidative deterioration and due to its chemical composition as well as its higher affinity to water, is considered to be a favorable substrate for microorganisms. On the other hand, apart from biodiesel, alcohols are considered to be promising substitutes to conventional diesel fuel because they can offer higher oxygen concentration leading to better combustion characteristics and lower exhaust emissions. More specifically, n-butanol is a renewable alcohol demonstrating better blending capabilities and properties when it is added to diesel fuel, as its composition is closer to conventional fuel, when compared ethanol to for example. Taking into consideration the alleged disinfectant properties of alcohols, it would be interesting to examine also the microbial stability of blends containing n-butanol in various concentrations. Based on the aforementioned, the aim of this study is to investigate the effect of n-butanol in diesel/ biodiesel blends on fuel quality characteristics (ignition quality, lubricity) while the oxidation and microbial stability is also assessed. Blends of automotive diesel with a commercial FAME up to 20% v/v and n-butanol at concentrations of 5% and 10% v/v were prepared. The microbial stability of diesel/biodiesel/n-butanol blends was assessed and compared to diesel-biodiesel ones by preparing and storing laboratory-scale contaminated microcosms. Overall, ULSD/FAME/n-butanol ternary blends demonstrated high blending stability while density, viscosity, CFPP and sulfur content have not been substantially affected. The poor lubricity of n-butanol and ULSD was compensated by the presence of FAME. N-butanol contributed in increasing the stability - either oxidation or microbial - of the ternary blends compared to the respective binary B7 and B20 blends. Nevertheless, FAME and n-butanol have poor ignition quality characteristics, which resulted in a significant decrease of the DCN of the base fuel.
Dodos, George S.Tsesmeli, Chrysovalanti E.Zahos-Siagos, IraklisTyrovola, TheodoraKaronis, DimitriosZannikos, Fanourios
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