Browse Topic: Rare earth metals

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This document provides risk mitigation for Pb-free solders used internal to parts used in Aerospace and Defense applications. It will include mitigations applicable to encapsulated and cavity devices as the needs arise in industry. Currently this revision only addresses devices with encapsulation or underfill. Mitigations for open cavity devices are still being discussed, and will be addressed in future revisions. Microbumps with Thermal Compression Bonding (TCB) are not addressed by the mitigations in this document. The use of Pb-free microbumps with TCB are considered out of scope at this time. It is expected that this document will be primarily used by Control Levels 3 and 2C (as defined in GEIA-STD-0005-2 for programs that do not allow use of Pb-free tin or only allow its use on an exception basis). It may be used by other levels, or by applications not using GEIA-STD-0005-2.
G-24 Pb-free Risk Management Committee for ADHP
This specification defines limits of variation for determining acceptability of the composition of cast or wrought titanium and titanium alloy parts and material acquired from a producer.
AMS G Titanium and Refractory Metals Committee
Toward Material Efficient Vehicles: Ecodesign Recommendations Based on Metal Sustainability Assessments05-11-03-00219/17/2018
Current End-of-Life Vehicle (ELV) recycling processes are mainly based on mechanical separation techniques. These methods are designed to recycle those metals with the highest contribution in the vehicle weight such as steel, aluminum, and copper. However, a conventional vehicle uses around 50 different types of metals, some of them considered critical by the European Commission. The lack of specific recycling processes makes that these metals become downcycled in steel or aluminum or, in the worst case, end in landfills. With the aim to define several ecodesign recommendations from a raw material point of view, it is proposed to apply a thermodynamic methodology based on exergy analysis. This methodology uses an indicator called thermodynamic rarity to assess metal sustainability. It takes into account the quality of mineral commodities used in a vehicle as a function of their relative abundance in Nature and the energy intensity required to extract and process them. This method is proposed as a tool to identify the most critical components in a vehicle so as to define specific ecodesign recommendations for them. The methodology is applied to a SEAT Leon 2.0 Diesel III model (segment C). Main recommendations are focused on reducing the use of metals with high thermodynamic rarity values such as Ag, Au, Cu, Ga, In, Pd, Pt, Sn, Ta, and Te. These metals are mainly used in electrical and electronic equipment. It is also recommended to reduce the disassembly time of a number of critical components such as airbag unit, electronic control unit, lighting switcher, antenna amplifiers, panel instrument, sensors, infotainment unit, light-emitting diodes (LEDs), and motors. A fast and easy disassembly would allow in subsequent phases to apply specific recycling processes based on mechanical and hydrometallurgical hybrid approaches instead of only mechanical separation techniques.
Ortego, AbelValero, Alicia
Sustainability and Production Economics of Titanium for Engine Valve: India Perspective2018-28-00027/9/2018
Automotive industry is looking to have breakthrough for utilization of titanium in vehicles with cost effective solution. This is due to the relative cost factor and for titanium it is 20 and 2.9 times greater than steel and aluminium respectively. Looking at Today’s scenario of multi material vehicle, it weighs approximately 221 kg on usage of conventional materials i.e. aluminium 37%, steel 42% and composites 21%. also Indian government has taken bold decision to meet BS VI norms directly by 2020 and to achieve the same it is required to meet NOx level of 0.06 g/km for gasoline vehicles and 0.080 g/km for diesel vehicle along with EGR rates of 35% at full load at which conventional materials like steel, aluminium has to withstand for high temperature cycles and high compressed air pressure at outlet. Hence positive progress of implementation of titanium by proving its production economy and sustainability for leading automotive components like exhaust system, valve train and turbocharger components in vehicles for the mass market is prime important. But focusing on mass market may not work effectively as total production of titanium i.e. ilmenite and rutile is about 522 thousand tonnes by 2016 and on the other hand vehicle production in India by 2016 was 24.015 million units. Considering usage of titanium in other sectors, titanium if contribute up to 2 kg /vehicle (48 thousand tonnes) may leads to proportionate increase in fuel economy, decrease in emission and increased titanium usage in vehicle by 9.2%. To do so automotive engineers, designers need to attack cost, manufacturing challenges and effective research and development on titanium ore extraction technology to make highly priced titanium user friendly for automotive industry. Detail discussion on addressed issues of titanium are discussed in this paper and to prove sustainability of titanium for automotive application metallurgical failure analysis of failed valve (inlet & exhaust) is carried out using spectroscopy, optical microscopy and scanning electron microscopy which clearly indicates need of titanium family for high temperature automotive components.
Garud, VikrantBhoite, SanjiwanPatil, SagarGhadage, SurajRawandale, Shitalkumar
This SAE Standard covers the hardness, chemical analysis and microstructural requirements for ductile iron castings intended for high temperature service in automotive and allied industries. Commonly known as SiMo ductile iron, typical applications are in piston-engine exhaust manifolds and turbocharger parts. Castings may be specified in the as-cast or heat treated condition. For design purposes, the Appendix provides general information on the application of high temperature ductile iron castings, their processing conditions, chemical composition, mechanical properties and microstructure.
Metals Technical Committee
This SAE Standard covers the most common magnesium alloys used in wrought forms, and lists chemical composition and minimum mechanical properties for the various forms. A general indication of the usage of the various materials is also provided.
Metals Technical Committee
This document has not changed other than to put it into the new SAE Technical Standards Board Format This SAE Standard covers the most commonly used magnesium alloys suitable for casting by the various commercial processes. The chemical composition limits and minimum mechanical properties are shown. Over the years, magnesium alloys have been identified by many numbering systems, as shown in Table 1. Presently, SAE is recommending the use of the use of the UNS numbering system to identify those materials. Other equally important characteristics such as surface finish and dimensional tolerances are not covered in this standard.
Metals Technical Committee
Synchronous Motor with Silicon Steel Salient Poles Rotor and All Coils Placed on the Stator2017-01-16063/28/2017
In this paper, we consider a new design of synchronous motor with salient poles rotor and all coils placed on the stator. This design, uses a laminated silicon steel rotor, which is not so expensive as a rotor with super strong permanent magnets. This design of machine eliminates copper rings on the rotor and brushes which is used in regular synchronous motors, and eliminates disadvantages involved with these arrangements. In an earlier publication, authors considered the opportunity realization of synchronous mode operation in the machine with salient pole rotor and DC stator excitation. Now, we consider the new synchronous mode operation with individual DC excitation of each the alternative current (AC) windings for realization the first, second and third phase synchronous machines. In theoretical basics of analyses and design of synchronous motors we pay more attention to the single-phase motor because it is the basis for design polyphase synchronous machines. In the paper, we suggest a new single-phase, two phase and three phase synchronous motor configuration. These synchronous machine configurations can work in DC mode operation without changing the electronic power circuit. This property can also be used for starting synchronous machines. The prototype, two phase synchronous motor was designed and tested. The single-phase motor was tested on the base two phase motor. Results of the test from these prototype machines confirm the main useful properties of synchronous machines.
Gladyshev, Sergey P.Gladyshev, PavelOkrainskaya, Irina
Development of Chemical Process for Recovering High-quality Rare-earth Oxides from HV Motor Magnets2017-01-12783/28/2017
In the automobile industry, interest in the prevention of global warming has always been high. The development of eco cars (HV, EV etc.), aimed at reducing CO2 emissions during operation, has been progressing. In the announcement of its "Toyota Environmental Challenge 2050", Toyota declared its commitment to creating a future in which people, cars, and nature coexist in harmony. In this declaration, Toyota committed to reducing CO2 emissions not only during operation but also over the entire life cycle of vehicles, and to using resources effectively based on a 4 R’s approach (refuse, reduce, reuse, and recycle). Although eco cars decrease CO2 emissions during operation, most of them increase CO2 emissions during manufacturing. For example, the rare-earths (Nd, Dy etc.) used in the magnets of driving motors are extracted through processes that produce a significant amount of CO2 emissions. The common process for recycling the rare-earths used in magnets can recover high-purity rare-earths by electrolysis. However, this process is costly and also produces a significant amount of CO2. Toyota has developed a chemical recycling process for producing high-quality rare-earth oxides that is economical and reduces CO2 emission during material production by 80% without the use of electrolytic refining. This paper describes this chemical recycling process for rare earth components and, in addition, introduces an energy-saving, vehicle-to-vehicle resource recycling flow.
Isomura, Keisuke
Materials scientists from North Carolina State University, Raleigh, NC, and Qatar University have developed a new high-entropy metal alloy that, they say, has a higher strength-to-weight ratio than any other existing metal material. High-entropy alloys consist of five or more metals in roughly equal amounts. The researchers say that strong, lightweight materials, may be very useful in prosthetic devices, as well as many other uses.
Engineers at Rutgers University, New Brunswick, NJ, say that a new medical imaging method they are developing may help physicians detect cancer and other diseases earlier than before, speeding treatment, and reducing the need for invasive, time-consuming biopsies. Their technique uses nanotechnology to reveal small cancerous tumors and cardiovascular lesions deep inside the body.
A new method has been developed to create coherent laser light efficiently with direct optical coupling of the Sun’s energy into the gain medium for multiple uses. New advances in solar cell photovoltaic (PV) technologies have greatly improved their efficiencies, mostly by improving their ability to convert many wavelengths or wider bands of the solar spectrum to electricity. New advances in actively doped fibers and optical glasses have been shown to produce very broad, multi-line absorption bands as well as stimulated emission lines, or laser lines. By designing the optical cavity system to feed back all emission bands into the gain media for amplification, a multi-wavelength source can be generated requiring no electronics.
Damage Mechanisms of Stainless Steels under Thermal Fatigue2014-01-09174/1/2014
Thermal fatigue of austenitic and ferritic stainless steel grades has been experimentally and numerically investigated. A special test has been developed to determine the thermal fatigue resistance of clamped V-shaped specimens. This test permits to impose thermal cycle by alternating resistance heating and air cooling. The thermal fatigue life of a specimen is expressed as the number of cycles to failure. For a given grade, the fatigue life depends on the maximal and minimal temperature of the cycle, holding time at the maximal temperature and specimen thickness. The advantage of this V-shape test is that it is a simple procedure quite representative of the thermal fatigue process occurring in an exhaust manifold. This test is well suited to perform a study of damage mechanisms and to compare stainless steel grades. Examination of the failed specimens indicated that cracks could be mainly attributed to out-of-phase (OP) thermal fatigue process especially in case of ferritic grades. For austenitic steels (AISI304 EN1.4301, AISI321 EN1.4541 or AISI308 EN1.4828) at a critical temperature or above, an in-phase (IP) thermal fatigue mechanism is coupled with oxidation and creep, which are further significantly reducing the lifetime. Therefore, the service temperature range of austenitic grades is more limited than ferritic grades. Despite their lower yield stress at high temperature, ferritic grades exhibit a very good thermal fatigue resistance at elevated peak temperatures because of their very good cyclic oxidation behavior, creep resistance and their low coefficient of thermal expansion. Consequently a dedicated titanium or niobium stabilized ferritic offer was developed for the hot part of the exhaust system (from manifold to catalytic converter) that includes 14%Cr (K11X 429/425 1.4595), 17%Cr (K41X 441 1.4509) and 19%Cr (K44X modified 444 1.4521) grades in order to cover the peak temperature range from 900°C to 1050°C.
Santacreu, Pierre-OlivierFaivre, LaurentAcher, Antoine
There are two types of voice coil actuators: moving coil and moving magnet. The materials of construction are similar, since they both use rare earth magnets, steel, copper wire, and basic insulation materials. There is a tendency to want to say one type is better suited for certain applications; however, there are many different sizes and shapes of voice coil actuators, making it difficult to make blanket statements about which type of actuator works better, and where.
Development of Rare Earth-saving Magnet Using Localized Diffusion Method2013-01-17574/8/2013
Nd₂Fe₁₄B sintered magnets are used in the drive motors of hybrid, electric and other vehicles. A magnet in which rare earth content is reduced by means of a localized diffusion method has been developed in order to reduce the volume of dysprosium. The distribution of the demagnetization fields in a motor is not uniform, so the necessary coercivity distribution for the magnets was quantified using Computer-Aided Engineering (CAE). Then material specifications of the localized dysprosium diffusion satisfied with this coercivity distribution was determined, and optimal manufacturing conditions including the position of dysprosium diffusion were set. The coercivity distribution in every position of the magnet using localized diffusion method was inspected. As a result, the magnet was satisfied with coercivity distribution demanded by CAE. Furthermore, evaluation of motor characteristics, especially the demagnetizing characteristic concerned with dysprosium reduction, showed this developed magnet to possess identical characteristics to a conventional magnet. Dysprosium resources represent a particular issue among the rare earths more generally, and the technology developed in this project is able to reduce dysprosium use in magnets by approximately 30% without compromising motor performance.
Higashi, TakayukiMiyoshi, TakehiroKato, RyutaroKono, MichihisaInoue, MasashiNagumo, ToshiyukiFukui, TakahiroOhsaki, KojiroIwasaki, Makoto
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