Browse Topic: Water reclamation

Items (119)
A method was developed that allows water recycling, air treatment, thermal control, and solid residuals treatment and recycle to be removed from the usable habitat volume and placed in the walls of a radiation-shielding water wall. This design also provides a mechanism to recover and reuse water treatment (solid) residuals to strengthen the habitat shell.
Solid Phase Extraction Mechanistic Studies of the Ag(I)-DMABR Complex: Improving Efficiency of the C-SPE Standard Method of Analysis2008-01-22006/29/2008
Aqueous silver(I) is added at trace levels (0.1 – 1.0 mg/L) to spacecraft potable water as a biocide. Development of a method that can be deployed on orbit and in future Lunar and Mars missions is therefore central to maintenance of safe drinking water and crew health. To address this need, our laboratory has created an analytical technique that couples a selective sorption process based on solid phase extraction (SPE) with the quantitative measurement of the extract by a hand-held diffuse reflection spectrophotometer. This technique, referred to as colorimetric-solid phase extraction (C-SPE), enables the low level detection (limit of detection ∼5 ppb) of silver(I) by metering 1.0 mL of a water sample through a reagent-impregnated (i.e., 5-(p-dimethyl-aminobenzylidene)rhodanine, DMABR) SPE membrane. The total workup time for the analysis is only 60-90 s. Moreover, the effectiveness of this method has been demonstrated by microgravity simulations through comparisons to concurrent ground-based analyses of companion samples. In keeping with the mission of our research, we are constantly refining the efficiency and effectiveness of our methodology. One pressing problem when using C-SPE in a microgravity environment is the presence of dispersed air bubbles that can lead to errors in exact measurement of sampling volumes. Our current protocol requires the withdrawal of more than the specified volume of analyte into a syringe and swinging the syringe in an arc to force the entrapped air to the tip. The air and excess sample are expelled into a waste container before ejecting the analyte through the extraction cartridge. The ideal situation would involve filling a syringe without concern for the exact sample volume, and this can be accomplished by applying the principles of negligible depletion (ND) in conjunction with C-SPE measurements. To determine if current C-SPE protocols could be manipulated to our advantage, a series of experiments were performed to gain a fuller understanding of the role of DMABR in complexing silver(I). Currently used SPE membranes were found to be highly efficient for retaining DMABR, suggesting that reagent loadings may be reduced without compromising extraction performance, posing the potential to adjust the amount of reagent in a membrane to manipulate ND volumes.
Siperko, Lorraine M.Porter, Marc D.Lipert, Robert J.
Lightweight Contingency Water Recovery System Concept Development2008-01-21436/29/2008
The Lightweight Contingency Water Recovery System (LWC-WRS) harvests water from various sources in or around the Orion spacecraft in order to provide contingency water at a substantial mass savings when compared to stored emergency water supplies. The system uses activated carbon treatment (for urine) followed by forward osmosis (FO). The LWC-WRS recovers water from a variety of contaminated sources by directly processing it into a fortified (electrolyte and caloric) drink. Primary target water sources are urine, seawater, and other on board vehicle waters (often referred to as technical waters). The product drink provides hydration, electrolytes, and caloric requirements for crew consumption. The system hardware consists of a urine collection device containing an activated carbon matrix (Stage 1) and an FO membrane treatment element (or bag) which contains an internally mounted cellulose triacetate membrane (Stage 2). All components are light weight disposable plastic, the system is potentially wearable, and it uses no electrical power. When treating urine and other wastewaters containing high levels of organic contaminates this two stage treatment process is required. Seawater and wastewaters containing low levels of organics can be treated for removal of inorganic contaminants (like the salt in seawater) and microorganisms using only the second stage FO membrane element. First year performance testing indicated acceptable flux rates and water recovery percentages over 6 to 12 hours of optimal urine treatment, when using the full system. Some challenges remained in achieving and evaluating acceptable contaminates flux/rejection rates for TOC and nitrogen species in the product; see ICES paper 2007-01-3037 (Gormly and Flynn, 2007). Year 2 work has focused on four basic areas: Characterizing performance of the Stage 2 FO membrane treatment to harvest seawater for use in post landing survival at sea. Researching alternative food product and components for use as the osmotic agent (OA). Pursuing better TOC confirmation in terms of total expected flux/rejection and characterization. In particular, research to confirm (TOC) flux measured in NaCl/ultra-pure water brine product solutions using high chloride compatible analysis methods. Increased nitrogen species control and characterization in the process and product, particularly investigating product side options for urea and/or ammonia nitrogen control. Of these tasks the first is complete, the second and third are in work with substantial data currently available and reported, and the last is in the initial stages of concept development and data collection. Concluding comments and discussion will include a synopsis of seawater, urine and technical water recovery concept development as well as some future options for developing this technology. Initially, the system's urine recycle function is intended for contingency/emergency use only, but will do so at a significant mass savings when compared to contingency water supplies and/or conventional water treatments. LWC-WRS Stage 2 can be exploited to provide emergency utilization of seawater and technical waters. Ultimately, further development of the technology may also provide options for better integration of water recycling into larger habitat component design by including FO membrane elements within the structures.
Gormly, SherwinRichardson, Tra-My JustineFlynn, MichaelKliss, Mark
The ISS Water Processor Catalytic Reactor as a Post Processor for Advanced Water Reclamation Systems2007-01-30387/9/2007
Advanced water processors being developed for NASA's Exploration Initiative rely on phase change technologies and/or biological processes as the primary means of water reclamation. As a result of the phase change, volatile compounds will also be transported into the distillate product stream. The catalytic reactor assembly used in the International Space Station (ISS) water processor assembly, referred to as Volatile Removal Assembly (VRA), has demonstrated high efficiency oxidation of many of these volatile contaminants, such as low molecular weight alcohols and acetic acid, and is considered a viable post treatment system for all advanced water processors. To support this investigation, two ersatz solutions were defined to be used for further evaluation of the VRA. The first solution was developed as part of an internal research and development project at Hamilton Sundstrand (HS), and is based primarily on ISS experience related to the development of the VRA. The second ersatz solution was defined by NASA in support of a study contract to Hamilton Sundstrand to evaluate the VRA as a potential post processor for the Cascade Distillation system being developed by Honeywell. This second ersatz solution contains several low molecular weight alcohols, organic acids, and several inorganic species. A range of residence times, oxygen concentrations and operating temperatures have been studied with both ersatz solutions to provide additional performance capability of the VRA catalyst.
Nalette, TimSnowdon, DougPickering, KarenCallahan, Michael
Microfluidic Ion Chromatograph for In-Flight Water Quality Analysis2007-01-31537/9/2007
Although water quality may currently be analyzed on the ground after a flight, long-duration missions will require the capability to perform analyses on-board. If a water purifier fails, contaminants must be detected rapidly and corrective action taken in a timely manner to prevent serious harm to the crew. Many of the possible contaminants which could negatively affect astronaut health are inorganic ions. These ions can be quantified by ion chromatography (IC), although current commercially-available IC's are too large, heavy, and power-intensive to be used on a space mission. These units also require large quantities of caustic chemicals for analysis, which would pose a significant hazard in a microgravity environment. To meet the need for an inorganic water quality analysis device for long-duration missions, Lynntech developed an ion chromatograph tailored for future planned long-duration missions. The entire unit is the size of a shoebox, requires little power, produces anionic and cationic chromatograms simultaneously, and generates the acid and base needed for analysis from benign salt water. Several components were developed specifically for this application over the course of work. A developed microfluidic liquid/gas phase separator performed successfully in microgravity conditions; a syringe pump was developed to provide uniform and repeatable high-pressure flow from a low-power, compact device; and a conductivity detector was designed and implemented with six orders of magnitude in dynamic range, an internal volume of only 0.7 microliters, and an autoranging capability which allows the analysis of both high and low ionic species concentrations in the same sample. The complete system and its measurement capabilities are described in detail.
Ragucci, TonyMaldonado, FranciscoRaducanu, MariusCisar, Alan
Alternative Physical and System Architectures for Membrane Based Advanced Regenerative Space Life Support System Water Processing2006-01-20837/17/2006
This study introduces new concepts in the function and placement of membrane based water treatment processes in Exploration Life Support (ELS) System design. These differences are in both form and function and have the potential to radically alter the current paradigms of thought within the ELS research community with regards to the limitations of conventional membrane water treatment. More importantly, they have the potential to change the placement of water processing by quite literally moving it “out of the box”, or in the case of ELS, the standard rack volume. Two possible systems, extremely small scale personal urine treatment and recycle (CEV Lightweight Contingency Water Treatment) and a similar but scaled up habitat wall embedded membrane water treatment pouch, are used to demonstrate the concepts involved. This work presents current membrane technology as an engineered material that can utilize a number of different treatment system architectures to achieve quite different treatment outcomes, when compared to traditional pressure fed membrane element based systems. Also, in treating membranes as an engineered material in integrative habitat and water processing design, other issues can be addressed by the water processor. Of particular interest is integrating water processing into radiation shielding (water wall) and flexible structural (zero pressurized volume mass metric) design. This makes the concepts covered of particular relevance to the radiation shielding designer and space architect, as well as the physical water treatment designer.
Gormly, SherwinFlynn, Michael
Carbon Production in Space from Pyrolysis of Solid Waste2006-01-21837/17/2006
Pyrolysis processing of solid waste in space will inevitably lead to carbon formation as a primary pyrolysis product. The amount of carbon depends on the composition of the starting materials and the pyrolysis conditions (temperature, heating rate, residence time, pressure). Many paper and plastic materials produce almost no carbon residue upon pyrolysis, while most plant biomass materials or human wastes will yield up to 20-40 weight percent on a dry, as-received basis. In cases where carbon production is significant, it can be stored for later use to produce CO2 for plant growth. Alternatively it can be partly gasified by an oxidizing gas (e.g., CO2, H2O, O2) in order to produce activated carbon. Activated carbons have a unique capability of strongly absorbing a great variety of species, ranging from SO2 and NOx, trace organics, mercury, and other heavy metals. Activated carbons can also be used for gas storage and gas separations, including systems of practical interest to NASA (e.g., CO2/N2/O2), and even for the purification of liquids. No single activated carbon is suitable for all applications, but appreciable control over sorbent properties can be exercised in the process of carbon preparation. Since activated carbons can be produced from a wide range of organic materials, including waste streams, the preparation of activated carbons on board spacecraft should involve a limited amount of additional resources, help manage on-board waste, and reduce the weight of materials to be launched from earth. A second source of carbon from pyrolysis processing of solid waste is carbon that results from cracking the primary pyrolysis liquids on a catalyst bed. This paper will examine the yields and reactivity characteristics of carbons formed in the first two stages of a prototype pyrolyzer from various solid wastes.
Serio, Michael A.Kroo, ErikWójtowicz, Marek A.Suuberg, Eric M.Wignarajah, KanapathipillaiFisher, John
Development of New Detection Schemes Using Colorimetric-Solid Phase Extraction for Formaldehyde and other Trace Organic Contaminants in Water2005-01-30637/11/2005
Space exploration by humans requires maintenance of an adequate potable water supply. Biocide levels must therefore be kept within allowable limits to prevent bacterial growth without causing adverse effects on crew health. Likewise, contaminants such as heavy metals and toxic organic compounds must be held at or below acceptable limits. Currently, spacecraft water quality analyses are performed on samples collected on the International Space Station and returned to Earth. Several months, however, can pass between sample collection and analysis, which may compromise sample integrity due to degradation. These delays also inhibit implementation of real time correction scenarios. There is, therefore, a critical need for rapid, on-board methods for monitoring trace quantities of several analytes in spacecraft drinking water supplies. We have previously described methods for monitoring the biocides iodine (I2) and silver(I), as well as the heavy metals nickel(II) and lead(II), by Colorimetric-Solid Phase Extraction (C-SPE). C-SPE is a sorption-spectrophotometric platform based on the selective extraction of analytes onto a membrane impregnated with a colorimetric reagent, followed by quantification on the membrane surface using a diffuse reflectance spectrophotometer. Building on our previous work, this paper describes recent progress in the development of a C-SPE platform for determining the contaminants formaldehyde and glycol, with detection limits as low as 4.6 ppb. In this method, which is the first to apply C-SPE to the determination of organic compounds, the requisite reagents will eventually be immobilized on inert media and packaged in an easy-to-use kit. These reagents are introduced during sample collection, forming a colored product that is exhaustively extracted onto an anion exchange membrane. The analyte concentration is determined on the membrane surface using diffuse reflectance spectroscopy. Details related to the first performance evaluations of this technique will be discussed.
Hazen-Bosveld, April A.Lipert, Robert J.Fritz, James S.Porter, Marc D.
Life Test Validation of Life Support Hardware in CONCORDIA Antarctic base2004-01-23527/19/2004
Given the constraints of the current launchers, manned exploration beyond LEO implies long time missions, a high mass of metabolic consumables and consequently regenerative life support technologies developments. To validate their efficiency, as well as their reliability, these technologies need to be tested in the most analog conditions (i.e. isolation, limited spare part, …). A large number of these conditions are met in the new permanent French-Italian settlement called Concordia, currently being built in the Antarctic continent. Over the last 15 years, ESA developed regenerative life support technologies. Two of these technologies: a Grey Water Treatment Unit and a Black Water Treatment Unit are currently assembled at the size of 15 to 70 persons to fulfill the Concordia crew needs The first technology is a multi step filtration system and will recycle the shower, washing machine, dish washer and cleaning water. The second technology, issued of MELiSSA project development, is composed of three bioreactors and will be used to process the fecal material, the urine and the kitchen wastes generated by the crew. The process is structured in three steps: a liquefaction, a methanogenic and a nitrifying step. Liquid effluents from this unit will then be further treated by the GWTU to produce hygiene water. The long-term life tests of these technologies will allow ESA to test regenerative life support technologies in the most realistic conditions. Technical parameters (i.e. efficiency, reliability,..) as well as human factors issues (i.e. psychology) will be continuously studied.
Lasseur, C.Angerer, O.Schmitt, D.Rebeyre, P.Amblard, P.Lasserre, J. C.Demey, D.Doulami, F.Michel, N.
Surfactant Biodegradation for Application to Advanced Life Support Water Recycling Systems2004-01-25137/19/2004
Complete reuse of graywater will be essential during long duration human space missions. The highest loaded and most important component to remove from graywater is surfactant, the active ingredient in soaps and detergents. When considering a biological treatment system for processing of graywater, surfactant biodegradability becomes a very important consideration. Surfactants should be chosen that are degraded at a fast rate and yield inconsequential degradation byproducts. Experiments conducted for this research examined the biodegradation of the surfactants in Pert Plus for Kids, disodium cocoamphodiacetate (DSCADA) and sodium laureth-3 sulfate (SLES), using respirometry. Rates of CO2 production, or ultimate degradation, are reported. DSCADA was found to be toxic to bacteria when present at 270 ppm whereas no toxicity was observed during experiments with SLES. Several surfactants were identified that may be encountered in a biological graywater treatment system including SLES, DSCADA, sodium alkyl benzene sulphonate, and alcohol ethoxylates. Biodegradation pathways for these surfactants are discussed and potential degradation byproducts are identified. Future experiments will focus on determination of Monod growth kinetics for the above listed surfactants as well as examination of the potential persistence of their metabolites within a water reuse system.
Sharvelle, SybilBanks, M. KatherineMaloney, Erin
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