Browse Topic: Battery cell chemistry

Items (174)
This study addresses safety concerns within the rapidly evolving Electric Vertical Takeoff and Landing (eVTOL) aircraft domain, focusing on efficient tools to quantify uncertainties in lithium-ion battery behavior - a critical aspect of eVTOL. One major issue with quantifying uncertainty is the prohibitive computational cost associated with many queries of an expensive-to-evaluate computational model. This work employs three physics-based battery models models of varying fidelity and cost to estimate the mean and the variance of the selected quantities of interest through a multifidelity method to reduce the computation cost. By combining information from multiple cheaper, lower-fidelity models through the Multifidelity Monte Carlo method, we significantly reduce the number of high-fidelity samples required for a prescribed mean-squared error, consequently reducing computational costs down to a tractable level. The proposed methodology is applied to estimate the mean and the variance of the battery temperature and voltage, accounting for uncertainties in flight conditions and materials. The first example focuses on a 580-second flight and is benchmarked against a standard Monte Carlo sampling technique. Results indicate a notable fourfold speed-up using the Multifidelity Monte Carlo method compared to the standard Monte Carlo method for the same mean-squared error for the voltage estimate. To showcase the method's generality, the multifidelity method is then applied to a longer flight of 3580 seconds for estimating the mean and the variance and utilizing these statistics to approximately estimate the probability of the flight completion. This demonstrates the adaptability of the methodology to various power profiles and considered uncertainties, with potential extensions to any battery chemistry. In conclusion, the presented multifidelity method offers a robust approach to enhance eVTOL safety by efficiently estimating uncertainties in battery behavior.
Diaz Flores Caminero, AlvaroKim, H. AliciaChaudhuri, AnirbanGuibert, Alexandre
This SAE Recommended Practice provides a set of test methods for characterizing lithium-ion battery electrolytes. These test methods are applicable to existing electrolyte materials and allow different facilities to conduct testing in a common manner. Solid electrolytes are expected to be commercially used for large scale batteries in the future. However, characterizing solid electrolytes may require methods different from those contained in this document. Such methods are not addressed in this document. It is not within the scope of this document to establish acceptance criteria for test results, as this is usually established between the vendor and customer. It is also not within the scope of this document to examine the electrochemical properties of an electrolyte, since these are influenced by electrolyte composition. In addition, establishing an electrolyte composition appropriate for all applications is not feasible.
Battery Materials Testing Committee
Brake Power Availability Led Optimisation of P0 versus P2 48V Hybrid Powertrain Architectures2020-01-04394/14/2020
Through improving the 48V hybrid vehicle archetype, governmental emission targets could be more easily met without incurring the high costs associated with increasing levels of electrification. The braking energy recovery function of hybrid vehicles is recognised as an effective solution to reduce emissions and fuel consumption in the short to medium term. The aim of this study was to evaluate methods to maximise the braking energy recovery capability of the 48V hybrid electric vehicle over pre-selected drive cycles using appropriately sized electrified components. The strategy adopted was based upon optimising the battery chemistry type via specific power capability, so that overall brake power is equal to the maximum battery charging power in a typical medium-sized passenger car under typical driving. This will maximise the regenerative braking energy whilst providing a larger torque assistance for a lower battery capacity. Dynamic simulation models were developed using GT-DRIVE software, emulating a mid-sized car with a 48V battery, and different turbocharged gasoline engines with motor-generator unit positions along a drivetrain. The 1.3 kWh battery pack was developed using a 14 Ah Lithium Iron Phosphate cell arranged in a 14 series 2 parallel configuration. A fuel economy comparison was produced using the FTP, WLTP, and HEFET drive cycles. When the motor-generator unit was attached via a synchronous belt, a 10-17% fuel saving was achieved in the WLTP drive cycle. Comparatively, when placing the electric machine after the clutch in a “P2” position, a 17-21% fuel saving was attained. The energy loss analysis of both P2 and P0 configurations revealed up to 7% overall reduction in total energy losses for the P2 setup. This was despite an increase in the motor-generator unit and battery losses due to the extended use of both in the electric-only mode capability with the P2 layout.
Alnamasi, KhaledTerry, SimonLa Rocca, AntoninoCairns, Alasdair
Methods for Leak Testing Lithium-Ion Batteries to Assure Quality with Proposed Rejection Limit Standards2020-01-04484/14/2020
A method is presented discussing how to reliably and quantitatively detect leakage from battery cells through the detection of escaping liquid electrolyte vapors, typically dimethyl carbonate (DMC). The proposed method does not require the introduction of an additional test gas into battery cells. The test system, which is non-destructive in nature, is applicable to non-rigid pouch cells and rigid prismatic or cylindrical cells. Lithium-ion batteries are a more suitable energy source for many applications because of their high energy density and low self-discharge rate. In the automotive powertrain sector, the lithium-ion battery market share is growing rapidly, with particularly high demand being placed on battery service life and safety. Requirements regarding maximum cell temperature, electrical load power or discharge power of the cell can be controlled by cooling and power management of the battery cell. A single defect in a cell housing can only be detected through leak detection of each battery cell. The lifetime of a battery strongly depends on the tightness of the cell housing, because of the harmful effects caused by the interaction between the electrolyte and water vapor. Rapid detection of leaks in the production of battery cells is absolutely essential to achieving necessary service life and safety requirements. This applies particularly to small leaks that cannot be detected immediately after the cell has been manufactured, for example by using an electrical discharge method. For pouch cells, no reliable method to detect small leak channels is available. This paper examines the spectrum of possible leak scenarios for cylindrical, prismatic and pouch lithium-ion batteries [Figure 1]. Currently no rejection limits have been codified for these batteries. INFICON has established empirically derived rejection limits that will be discussed in this paper.
Wetzig, DanielReismann, Maximillian
Replacement of a 50cc Two-stroke Engine with an Electric Powertrain2019-32-06231/24/2020
As global regulations look to create a dramatic reduction in CO2 emission and other forms of pollution, companies with products that rely on engine technology must be ready to take on the electrification challenge. Applications that remain using two-stroke engine technology continue to exist due to their very high power density requirements. However, their history of higher pollution compared to four-stroke engines makes them a target to be regulated out of existence. Such high power two-stroke applications include high performance off-road motorcycles. In this type of product, electrification can solve not only pollution challenges but market challenges, such as ridership and public perception. By addressing the core problems presented by the two-stroke engine and turning challenges into opportunity, a strong attraction is created to convert a two-stroke engine motorcycle to an electric vehicle. With Automotive electric vehicle technology paving the way, the basis for cost effective electric motorcycle powertrain is explored for a 50cc off-road motorcycle application. The 50cc engine and motorcycle represent a special product where size, performance, and cost have a high sensitivity. The 50cc product also represents an area of great opportunity for the product as it is connected to the youth riding segment that establishes the future of motorcycle riding. With both strong opportunity and strong challenges, the electrification solution for a 50cc application provides broad justification for mass market adoption across the motorcycle industry. Challenges will be presented towards a OEM level product where design change is to be minimized without compromising performance. Various challenges include system design, packaging, supply chain, product lifecycle, competition readiness, safety, and cost. Opportunities will be discussed in the context of how the electrified powertrain can create a better product for the rider and solve challenges to enable the next generation of motorcycling. These opportunities include manufacturing advantages, environmental harmony, and new features.
Beeker, Jesse
xEVs involved in incidents present unique hazards associated with the high voltage system (including the battery system). These hazards can be grouped into three categories: chemical, electrical, and thermal. The potential consequences can vary depending on the size, configuration, and specific battery chemistry. Other incidents may arise from secondary events such as garage fires and floods. These types of incidents are also considered in the recommended practice (RP). This RP aims to describe the potential consequences associated with hazards from xEVs and suggest common procedures to help protect emergency responders, tow and/or recovery, storage, repair, and salvage personnel after an incident has occurred with an electrified vehicle. Industry design standards and tools were studied and where appropriate, suggested for responsible organizations to implement. Lithium ion (Li-ion) batteries used for vehicle propulsion power are the assumed battery system of this RP. This chemistry is the prevailing technology associated with high voltage vehicle electrification today and the foreseeable future. The hazards associated with Li-ion battery chemistries are addressed in this RP. Other chemistries and alternative propulsion systems including hydrogen fuel cells are not considered in this version of SAE J2990. Recommendations for hazards associated with hydrogen vehicles can be found in SAE J2990/1.
Hybrid - EV Committee
Design of a Grid-Friendly DC Fast Charge Station with Second Life Batteries2019-01-08674/2/2019
DC-fast charge (DCFC) may be amenable for widespread EV adoption. However, there are potential challenges associated with implementation and operation of the DCFC infrastructures. The integration of energy storage systems can limit the scale of grid installation required for DCFC and enable more efficient grid energy usage. In addition, second-life batteries (SLBs) can find application in DCFC, significantly reducing installation cost when compared to solutions based on new battery packs. However, both system architecture and control strategy require optimization to ensure an optimal use of SLBs, including degradation and thermal aspects. This study proposes an application of automotive SLBs for DCFC stations where high power grid connection is not available or feasible. Several SLBs are connected to the grid by means of low power chargers (e.g. L2 charging station), and a DC/DC converter controls the power to the EV power dispenser. The architecture of the DC bus, the size and state of health of the battery system determine efficiency, cost, and reliability of the station. A technical and economic comparison is proposed, evaluating solutions with different battery pack sizes and control strategies. An accurate numerical model is used to evaluate the performance of the different architectures. A realistic usage profile of the charging station is defined and real-world scenarios are considered for the SLB parameters.
D'Arpino, MatildeCancian, Massimo
Pushing the Energy Limits of Lithium Ion Batteries through Fluorinated Materials2019-01-05954/2/2019
The use of electrolytes containing small fluorinated molecules to enable stable high voltage (>4.3 V) battery operation is the focus of this project. Previously, it has been shown that it is possible to operate lithium ion batteries utilizing several different cathode chemistries up to 4.5 V. Energy gains of 30-50% have been demonstrated when the battery is cycled at 4.5 V. High voltage cycling is accomplished by reducing the gas generation originating from electrolyte decomposition at high voltage. The primary mechanism for this is not completely understood, but the hypothesis is that the fluorinated molecules form a film on the highly oxidizing cathode. The protective film formation allows stable cycle life during high voltage operation. In addition, fluorinated electrolytes have the added benefit of being less flammable which increases safety performance of lithium ion batteries. Highly fluorinated binder materials offer a variety of advantages (lower modulus, higher chemical resistance, better temperature stability) over the conventional PVDF binders used in current lithium ion batteries. Use of these highly fluorinated binder additives has a direct impact on battery manufacturing costs through decreased scrap rate. This is achieved through higher slurry stability (improved mixing, coating) and more flexible physical characteristics (improved winding). The trend towards higher voltage battery operation will also require increased binder stability. This paper will address the advantages of both fluorinated electrolytes and binder materials as well as their role in future battery production.
Sunstrom, JosephFalzone, AlecGilmore, MichaelHendershot, RonMeserole, ChadSandoval, AbundioGrumbles, EmilyCosta, MelissaHaque, Arsela
Design of an energy storage system with blended of Li-ion batteries for pure electric vehicle of high performance2018-36-01809/3/2018
The state of art in Li-ion cells has one technologic gap to find in the same cell all requirements of performance to a vehicle that need high impulse and high autonomy combined. Certain Li-ion cells have characteristics of high energy density that exhibit high voltage and high rate capability, but have poor cycling and low power capacity. Alternately, other types of cells have high power density exhibit good thermal stability, good cycling, and high rate regime operation characteristics but have low rate capability and low voltage. Blending different cathode Li-ion cells in the same Energy Storage System is a new approach to design the better batteries for Pure Electric Vehicle of High Performance. This paper is intended to develop an Energy Storage System that take the advantage of the unique properties of each electric type of Li-ion cell and optimize its performance with respect to the automotive operating requirements. Therefore is presented the constrain requirements for selection of the batteries, the performance results, the thermal design considerations, the differences of strategies of state estimators and balancing of charge, the differences in hardware of battery management system as well as are discussed the energy balance during determined drive cycle operation. Several simulations based in model based design was performed considering the differences in the parameterization of each type Li-ion cells as well several laboratory tests have realized for validation of the design.
Santos, Sender Rocha dosAranha, Juliana C. M. S.Cerri, Fernando AugustoNascimento, Thiago Chiachio doRosolem, Maria de Fátima Negreli CamposSansão, Juliano C.Hamacek, Paulo Vitor B.Guillaumon, Fábio Zilse
Efficient Electro-Thermal Model for Lithium Iron Phosphate Batteries2018-01-04324/3/2018
The development of a comprehensive battery simulator is essential for future improvements in the durability, performance and service life of lithium-ion batteries. Although simulations can never replace actual experimental data, they can still be used to provide valuable insights into the performance of the battery, especially under different operating conditions. In addition, a single-cell model can be easily extended to the pack level and can be used in the optimization of a battery pack. The first step in building a simulator is to create a model that can effectively capture both the voltage response and thermal behavior of the battery. Since these effects are coupled together, creating a robust simulator requires modeling both components. This paper will develop a battery simulator, where the entire battery model will be composed of four smaller submodels: a heat generation model, a thermal model, a battery parameter model and a voltage response model. The paper will provide a brief description on each of these four sub-models and how they are correlated with each other. In addition, this work will examine the significance of accounting for the reversible heat generation term when predicting battery temperature. The obtained comprehensive model will then be validated by testing on a 20 Ah lithium iron phosphate battery. The results show that the electro-thermal model can adequately capture both the voltage and thermal trends in the battery. In addition, the findings indicate that accurate tracking of the curvature present in the temperature profile during discharge/charge can only be accomplished by including the reversible heat generation component in the overall model. These findings are beneficial for battery design and optimization in future applications.
Mathew, ManojMastali, MehrdadCatton, JohnSamadani, EhsanFowler, Michael
Modeling and Validation of 48V Mild Hybrid Lithium-Ion Battery Pack2018-01-04334/3/2018
As part of the midterm evaluation of the 2022-2025 Light-Duty Vehicle Greenhouse Gas (GHG) Standards, the U.S. Environmental Protection Agency (EPA) developed simulation models for studying the effectiveness of 48V mild hybrid electric vehicle (MHEV) technology for reducing CO2 emissions from light-duty vehicles. Simulation and modeling of this technology requires a suitable model of the battery. This article presents the development and validation of a 48V lithium-ion battery model that will be integrated into EPA’s Advanced Light-Duty Powertrain and Hybrid Analysis (ALPHA) vehicle simulation model and that can also be used within Gamma Technologies, LLC (Westmont, IL) GT-DRIVE™ vehicle simulations. The battery model is a standard equivalent circuit model with the two-time constant resistance-capacitance (RC) blocks. Resistances and capacitances were calculated using test data from an 8 Ah, 0.4 kWh, 48V (nominal) lithium-ion battery obtained from a Tier 1 automotive supplier, A123 Systems, and developed specifically for 48V mild hybrid vehicle applications. The A123 Systems battery has 14 pouch-type lithium-ion cells arranged in a 14 series and 1 parallel (14S1P) configuration. The RC battery model was validated using battery test data generated by a hardware-in-the-loop (HIL) system that simulated the impact of MHEV operation on the A123 systems 48V battery pack over U.S. regulatory drive cycles. The HIL system matched charge and discharge data originally generated by Argonne National Laboratory (ANL) during chassis dynamometer testing of a 2013 GM Chevrolet Malibu Eco 115V MHEV. All validation testing was performed at the battery test facility (BTF) at the U.S. EPA National Vehicle and Fuel Emissions Laboratory (NVFEL) in Ann Arbor, Michigan. The simulated battery voltages, currents, and state of charge (SOC) of the HIL tests were in good agreement with vehicle test data over a number of different drive cycles, and excellent agreement was achieved between RC model simulations of the 48V battery and HIL battery test data.
Lee, SoDukCherry, JeffSafoutin, MichaelMcDonald, JosephOlechiw, Michael
Nickel Cadmium Vented Rechargeable Aircraft Batteries (Non-Sealed, Maintainable Type)AS8033 (Current)10/26/2017
The Nickel Cadmium battery covered by this Aerospace Standard is the type which is generally, although not exclusively, used for engine starting purposes in turbine-powered aircraft and/or on aircraft with turbine type Auxiliary Power Units. This turbine starting function requires high power delivery rates from the battery for 15 to 30 seconds or more for each engine start. This same battery may also be used at lower power delivery rates, as the final redundant source of emergency electrical energy for the operation of essential flight equipment for required periods of 30 to 60 minutes. The battery generally consists of a group of plastic jarred cells contained within an enclosing battery case. They are electrically connected in series with each other and usually terminate in an electrical connector mounted in the case front wall. The battery case may be secured to the aircraft structure by any of a number of clamping techniques. The outer or battery case is ventilated to purge it of gases, such as the hydrogen and oxygen produced in overcharge. This ventilation may be of the closed air circuit type which is accomplished by passing air through the case and then exhausting these gases overboard. An alternative method, which is used to purge these gases from the battery case, is to encourage their natural convective diffusion with the ambient air in the compartment which contains the battery, by use of relatively open construction of the battery case and cover. The battery, while in service, is generally charged by one of two methods: 1) by direct electrical connection to the D.C. bus which in turn is supplied by a regulated/controlled “constant potential” source such as a D.C. generator, or 2) from a dedicated “constant current” source in a system whereby the battery response voltage controls the termination, and also possibly the reinitiation, of that charge current. The “control” voltage of the “constant current” charge system or the regulated supply voltage of the “constant potential” system, may be compensated, or automatically adjusted, according to cell temperature, in order to more accurately control the state of “full charge” and minimize the amount of water used during overcharge. These batteries may be equipped internally with heaters, thermal switches, thermal sensors, etc. for performing various functions both inside the battery and/or in the aircraft/battery system. In addition, some battery types have air passages between cells with appropriate plenum chambers above and below the cells, for more positive responsive control of cell temperature, by the passage of conditioned air.
AE-7B Power Management, Distribution and Storage
Automatic Generation of Online Optimal Energy Management Strategies for Hybrid Powertrain Simulation2017-24-01739/4/2017
Due to more and more complex powertrain architectures and the necessity to optimize them on the whole driving conditions, simulation tools are becoming indisputable for car manufacturers and suppliers. Indeed, simulation is at the basis of any algorithm aimed at finding the best compromise between fuel consumption, emissions, drivability, and performance during the conception phase. For hybrid vehicles, the energy management strategy is a key driver to ensure the best fuel consumption and thus has to be optimized carefully as well. In this regard, the coupling of an offline hybrid strategy optimizer (called HOT) based on Pontryagin’s minimum principle (PMP) and an online equivalent-consumption-minimization strategy (ECMS) generator is presented. Additionally, methods to estimate the efficiency maps and other overall characteristics of the main powertrain components (thermal engine, electric motor(s), and battery) from a few design parameters are shown. Finally, the use of such tool chain to automatically generate the optimal energy management strategy for a given hybrid powertrain configuration, for which the main components are sufficiently specified and characterized is presented. The powertrain configuration illustrating this work is an input-split hybrid configuration.
Dabadie, Jean-CharlesSciarretta, AntonioFont, GregoryLe Berr, Fabrice
Internal Cell Temperature Measurement and Thermal Modeling of Lithium Ion Cells for Automotive Applications by Means of Electrochemical Impedance Spectroscopy2017-01-12153/28/2017
Battery safety is the most critical requirement for the energy storage systems in hybrid and electric vehicles. The allowable battery temperature is limited with respect to the battery chemistry in order to avoid the risk of thermal runaway. Battery temperature monitoring is already implemented in electric vehicles, however only cell surface temperature can be measured at reasonable cost using conventional sensors. The internal cell temperature may exceed the surface temperature significantly at high current due to the finite internal electrical and thermal cell resistance. In this work, a novel approach for internal cell temperature measurement is proposed applying on board impedance spectroscopy. The method considers the temperature coefficient of the complex internal cell impedance. It can be observed by current and voltage measurements as usually performed by standard battery management systems. The relevant frequency range considered for temperature measurements is chosen for high sensitivity and robust behavior and takes state of charge variations as well as aging effects into account. Transient temperature variations caused by various load profiles are analyzed in order to characterize the static and dynamic thermal properties of the cell. The resulting thermal equivalent model describes temperature changes inside the cell dependent on load current and ambient temperature. The temperature measurement approach and the thermal model are suitable for on board implementation in battery management systems. A dedicated battery excitation is not required, as signal components in the relevant frequency range are inherently present in typical driving current profiles. Thereby, significant improvements in terms of on-board diagnostics and battery safety can be achieved without any additional hardware effort.
Haussmann, PeterMelbert, Joachim
Online Optimization based Predictive Energy Management Functionality of Plug-In Hybrid Powertrain using Trajectory Planning Methods2017-01-12543/28/2017
Powertrain systems exploiting information from vehicle connectivity have widened the system boundary resulting in additional degrees-of-freedom for predictive trajectory planning. Heuristic methods based on component characteristics are currently widely used for Energy Management (EM) functionality of hybridized powertrains. Despite their better usability, increased calibration effort and sensitivity to synthetic calibration scenarios are drawbacks of such control methods. Availability of predictive data, better computing power and challenges posed by various scenarios in real driving, have led to interest in online-optimizing EM functionality. Equivalent Consumption Minimization Strategy (ECMS) approaches based on Indirect optimal control /Pontryagin Minimum principle have difficulty in handling inequality state constraints. Extensions of ECMS make use of modifications to the equivalence factor/co-state, based on prediction of driving conditions. The proposed method uses limited time horizon prediction data to optimize engine on/off state and torque split among the energy converters using direct optimal control. Along with its ability to handle inequality constraints on the system states directly, the proposed method does not require an explicit model of additional dynamics. Further, the developed EM functionality adapts in real-time based on situation-aware prediction along with offering possibility to tune online the optimization process using heuristics on constraint-limits. These advantages along with this real-time capability and flexibility to handle change of control objectives as well as variation of control weighting reduces calibration effort. Results of the functionality shall be compared with predictive ECMS method. The functionalities developed along with their real-time capability will be demonstrated using the Combustion Engine Assist (CEA) concept.
Vadamalu, Raja SangiliBeidl, Christian
Modeling and Validation of 12V Lead-Acid Battery for Stop-Start Technology2017-01-12113/28/2017
As part of the Midterm Evaluation of the 2017-2025 Light-duty Vehicle Greenhouse Gas Standards, the U.S. Environmental Protection Agency (EPA) developed simulation models for studying the effectiveness of stop-start technology for reducing CO2 emissions from light-duty vehicles. Stop-start technology is widespread in Europe due to high fuel prices and due to stringent EU CO2 emissions standards beginning in 2012. Stop-start has recently appeared as a standard equipment option on high-volume vehicles like the Chevrolet Malibu, Ford Fusion, Chrysler 200, Jeep Cherokee, and Ram 1500 truck. EPA has included stop-start technology in its assessment of CO2-reducing technologies available for compliance with the standards. Simulation and modeling of this technology requires a suitable model of the battery. The introduction of stop-start has stimulated development of 12-volt battery systems capable of providing the enhanced performance and cycle life durability that it requires. Much of this activity has involved advanced lithium-ion chemistries, variations of lead-acid chemistries, such as absorbed-glass-mat (AGM) designs, and lead-carbon formulations. EPA tested several AGM batteries that are used in OEM start-stop systems. The purpose of this testing was to develop an equivalent circuit model for integration into EPA's ALPHA vehicle simulation model. Testing was performed at the Battery Test Facility (BTF) at the U.S. Environmental Protection Agency (EPA) National Vehicle and Fuel Emissions Laboratory (NVFEL) in Ann Arbor, Michigan. The Duracell batteries referenced are model number SLI49AGM with a rating of 92 Ah and the X2 Power batteries referenced are model number SLI34-78AGMDP with a rating of 68 Ah. Both batteries are 6 cell 12 volt using AGM technology. For compatibility with the voltage specifications of the BTF equipment, tests were performed on two batteries connected in series (nominal 24 volts). This paper presents the development and validation of the lead-acid battery model. The battery model is a standard equivalent circuit model with two Resistance-Capacitance (RC) blocks. Resistances and capacitances were calculated using test data from a Duracell 92Ah lead-acid battery which is aftermarket equipment for the Chevrolet Malibu. The lead-acid battery library in the ALPHA model was validated with data obtained from Argonne National Laboratory (ANL) from their chassis dynamometer testing of the 2010 Mazda 3 Hatchback i-Stop [9] and 2010 VW Golf TDI Diesel Bluemotion [10]. The simulated battery voltages, currents, and state of charge (SOC) are in excellent agreement with the vehicle test data on a number of drive schedules.
Lee, SoDukCherry, JeffSafoutin, MichaelMcDonald, Joseph
Potential Cost Savings of Combining Power and Energy Batteries in a BEV 3002016-01-12134/5/2016
Present-day battery technologies support a battery electric vehicle with a 300mile range (BEV 300), but the cost of such a vehicle hinders its large-scale adoption by consumers. The U.S. Department of Energy (DOE) has set aggressive cost targets for battery technologies. At present, no single technology meets the cost, energy, and power requirements of a BEV 300, but a combination of multiple batteries with different capabilities might be able to lower the overall cost closer to the DOE target. This study looks at how such a combination can be implemented in vehicle simulation models and compares the vehicle manufacturing and operating costs to a baseline BEV 300. Preliminary analysis shows an opportunity to modestly reduce BEV 300 energy storage system cost by about 8% using a battery pack that combines an energy and power battery. The baseline vehicle considered in the study uses a single battery sized to meet both the power and energy requirements of a BEV 300. The alternate option considered is a combination of two battery packs controlled by a power conditioner. The energy battery has lithium sulphur (Li-S) cells, and the power battery has lithium manganese oxide (LMOG) cells. The Li-S and LMOG cells have different cost characteristics. While it is relatively cheap to increase the capacity of an energy battery, adding more power to an energy battery is expensive. Similarly, more discharge power capability can be inexpensively added to the power battery, but storing more energy in that battery is expensive. However, it should be noted that this approach is not compatible with a high-rate, fast-charging requirement. This study looks at the levelized cost of driving (LCOD) for BEV 300s when different battery types and combinations are used.
Vijayagopal, RamGallagher, KevinLee, DaeheungRousseau, Aymeric
Temperature Characteristics of Ternary-Material Lithium-Ion Battery for Vehicle Applications2016-01-11964/5/2016
Traction batteries are operated in severe working conditions of wide temperature range as the vehicles run in different seasons and regions, which effects battery performance deeply. Investigation on the effect of temperature under such circumstances on battery performance is very significant to promote the application of traction battery. In this paper, some tests are conducted on a ternary-material lithium-ion battery at various temperatures. The cycling performance and some significant parameters are evaluated at the whole temperature range, especially at the extreme temperatures (below -10°C or above 45°C). The results show that the battery performance becomes poor obviously at low temperatures, which is reflected in the decreased terminal voltage and the faded discharge capacity, and at too high temperatures (above 45°C), power and capacity also decrease, which happens in the later period of discharge process. The rise of pure ohmic resistance is the main factor to limit battery discharging at low temperatures, and the discharge performance becomes poor at the very high temperatures that may be attributed to the substantially increased polarization resistance in the later period of discharge process. Compared with the effect of high temperature on battery, the effect of low temperature is extremely conspicuous, and from the perspective of battery application on vehicle, the variation of battery performance should be paid more attention when the discharge operating temperature is below 5°C.
Guo, YazhouLuo, MajiZou, JiaLiu, YunpengKang, Jianqiang
Simultaneous Estimation of the SOC and Parameters of Batteries for HEV/EV2016-01-11954/5/2016
This paper proposes a battery state estimation on a battery management system (BMS) for hybrid electric vehicles (HEVs) and electric vehicles (EVs). It is important to estimate a state of charge (SOC) and parameters of the battery such as a state of health (SOH), internal resistances and dynamics of electrochemical reactions. The BMS can provide information on the driving range of the EVs to the drivers by accurately estimating SOC and SOH. It can also calculate a state of power (SOP) to use the battery safely by accurately estimated SOC, internal resistances and others. For that purpose, this paper proposes the BMS adopted a simultaneous state of charge (SOC) and parameter estimation method using log-normalized unscented Kalman filter (LnUKF). The key idea is a lognormalization of the parameters to improve numerical stability and robustness of the algorithm. The proposed system is verified by a series of simulations using experimental data with EVs. One of the SOC and parameter estimation results is for low temperature data on the chassis dynamometer. The proposed system can accurately estimate SOC and parameters of the battery without relying on the experimentally obtained data even if it is under the harsh conditions such as low temperature environment. As a result, it can accurately estimate SOH and SOP of the battery since they are estimated by using estimates of SOC and parameters of the battery.
Baba, AtsushiItabashi, KinnosukeTeranishi, NozomuEdamoto, YoshihiroOsamura, KensukeMaruta, IchiroAdachi, Shuichi
Semiconductor chip technology has miniaturized by leaps and bounds over the past couple of decades, enabling the modern era we live in with smartphones, tablets, and small electronic gadgets everywhere. However, battery technology, which provides the lifeblood to power these devices, has been at a near standstill since the commercial availability of lithium-ion batteries in the early 1990s. In no other application is this discrepancy more profound than in medical implants.
There is a great need for energy sources that can power unattended sensors for more than a decade. Unattended sensors can be located in harsh and remote locations that are often dangerous for personnel maintenance and power source replacement. The power source must last the lifetime of the sensor. Unlike chemical batteries, the higher energy densities of radioisotopes allow the sensors to operate for infrastructure lifetimes (~150 years). Isotope batteries (iBATs) have the potential to become reliable, robust, and maintenance-free power sources for remote, long-term, low-power sensors. iBATs are different from chemical batteries because they are self-contained energy sources using radioisotope decay.
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