Magnet wire is composed of conducting core and thin layer of electrical insulation. Cupper (Cu) is typically used as conducting core, and various polymers such as polyamideimide, polyimide, and polyesterimide are used for electrical insulation. The role of magnet wire is involved in interchanging between electrical energy and mechanical energy for energy transformation application such as transformer, motor, generator, and many other equipment. Currently, electric vehicles (EV) industry is rapidly growing and consequential demands on related components are increasing as well. Compared to combustion engine, EV needs more electrical power with higher voltages or higher currents, which can increase probability of electrical discharge. The degradation of insulation layer can happen with the polymer bond breakage under the partial discharge electric stresses. To keep high performance under higher voltage, insulating polymer should have high heat resistances, chemical resistance, and low