Browse Topic: Kerosene

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Cloud Point Depressant Response Effects in Ultra-Low-Sulfur Diesel Fuel2005-01-389810/24/2005
Cloud point depressants (CPD) have been successfully used for many years in low-sulfur diesel fuels. For over ten years, custom-designed, specialty polymer chemistry has enabled refiners to meet cloud point (CP) guidelines with substantially less kerosene. This translates into greater refined yields through cut-point adjustment upgrades and the potential for diverting kerosene to more lucrative market opportunities, such as jet fuel. The practice of cut-point downgrades to gas oil can be costly because diesel fuel generally has greater value. Kerosene dilutions have historically been as high as 30%-40% by volume with low-sulfur diesel fuels [1, 2]. While kerosene addition enables fuels to reach CP guidelines, it may negatively impact the fuel's energy content, cetane number, lubricity, flash point and density. Properly designed CP additives are able to substantially reduce or even eliminate the need for kerosene, thus substantially reducing refinery costs. With ultra-low-sulfur diesel (ULSD) fuels being mandated throughout the mass market distribution system by June 2006, the need for CP control may be greater than ever. However, waxy crude and process limitations may make it difficult for refiners to economically make low cloud point ULSD. Fortunately, CPD can overcome these limitations without negatively impacting fuel characteristics. These additives allow refiners to meet low-temperature objectives while being neutral or beneficial to most other diesel fuel properties.
Pistillo, W. RoccoCerda de Groote, Carlos L.
Using Cloud Point Depressants Opportunistically To Reduce No.2 Diesel Fuel Cloud Point Giveaway2001-01-19275/7/2001
Diesel fuel is a blend of various middle distillate components separated at the refinery. The composition and characteristics of the diesel fuel blend changes daily if not hourly because of normal process variation, changing refinery processing conditions, changing crude oil diet or changing diesel fuel and kerosene market conditions. Regardless of the situation going on at the refinery or the market, the resultant diesel fuel must consistently meet established cloud point specifications. To consistently meet the cloud point specifications, refiners are forced to blend their diesel fuels in such a way that the resultant blend is always on the low side of the cloud point specification even when the refining process adversely changes the fuel characteristics. This practice has the effect of producing several degrees of cloud point “giveaway” when the refinery is not experiencing adverse swings in product quality. This designed “giveaway” costs the refinery money by not letting the refinery optimize the value of their blend components. By blending diesel fuel components closer to the cloud point specification or by raising distillation cut points, and only using cloud point depressants opportunistically to remediate over specification fuel blends, refiners can minimize cloud point giveaway, optimize their profit and market a more consistent diesel fuel product. This paper discusses a statistical analysis of “cloud point giveaway”, the economics of cloud point giveaway, and shows how refiners can reduce cloud point giveaway to maximize refinery profit and help produce a more consistent diesel fuel product.
Manka, John S.Lindenfelser, Eric A.Heller, Fred E.
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